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Mowgli, The Jungle Book (1967)
This "man cub" is our protagonist. Discovered lying in the wreckage of a boat in the middle of the jungle, Mowgli is raised by a pack of wolves who adopt him as their own. When news that Shere Khan — a dangerous, man-eating tiger — has returned to the jungle, it is decided that Mowgli must return to the "Man Village" to be with his own kind.
P.S.: You've been pronouncing Mowgli wrong this whole time. According to ScreenCrush,"The first syllable of Mowgli's name rhymes with 'cow' rather than 'show.'"
Kaa, The Jungle Book (1967)
We hate to be the ones to point this out, but Kaa is kind of useless. When he's not trying (and failing) to hypnotize Mowgli, Bagheera, and Baloo in order to eat them, he serves as a bumbling accomplice to Shere Khan. (He fails at both tasks.)
And if you're ohhhh bother-ed trying to puzzle why he sounds so familiar: Sterling Holloway also originated the voice of Winnie the Pooh.